What Does Gibbs Free Energy Tell You

By | October 23, 2021



Most of us are familiar with the basics of thermodynamics and how it explains the flow of energy within our physical world. But for those of us who want to understand the more intricate workings of thermodynamics, Gibbs Free Energy is an essential concept to understand. Gibbs Free Energy, or GFE, provides insight into the amount of energy available in a given thermodynamic system, and can be used to determine the feasibility of a reaction. In this article, we'll explore what exactly Gibbs Free Energy is, how it works, and how it affects our lives.

Gibbs Free Energy can be thought of as the energy that is available to do work after accounting for the energy already present in a system. It was first proposed by Josiah Willard Gibbs in 1873 and is often referred to as "available energy" or "free energy". Unlike other forms of energy, GFE is not directly measurable, rather it is inferred from other thermodynamic measurements, such as pressure and temperature, and further calculations. GFE plays an important role in determining whether or not a reaction will take place, and if so, how much energy is required for it to happen. Let's take a closer look at GFE and its implications for thermodynamics.

The concept of Gibbs Free Energy is closely related to the energy needed for a reaction to occur. When trying to figure out if a reaction will occur, we must consider how much energy is available in the system to use. The total amount of energy available is known as the free energy, and it is calculated as the difference between the energy of a system and the energy of its products. For example, if we take a reaction that involves converting nitrogen and oxygen into nitric acid, then we would calculate the free energy of the reaction by subtracting the energy of the nitric acid from the energy of the nitrogen and oxygen. If the difference is positive, then we know that the reaction will occur and it will require a certain amount of energy.

This amount of energy is known as the "Gibbs Free Energy" or "GFE". To put it simply, GFE is the amount of energy that is available in the system to make a reaction possible. To understand GFE, it is also important to understand the laws of thermodynamics. Thermodynamics is the study of how energy is exchanged between systems, and the laws of thermodynamics dictate how energy is used in a reaction. Specifically, the first law states that energy is neither created nor destroyed, but instead can be converted from one form to another. The second law states that entropy (disorder) always increases, meaning that energy in a system will naturally move from a more ordered state to a less ordered state.

In light of these two laws, GFE can be thought of as the amount of energy available in a system to do work, while still adhering to the laws of thermodynamics. This energy is expressed as a difference between the energy of the reactants and the energy of the products, and is usually expressed in kilojoules (kJ). GFE is important because it helps us determine how much energy needs to be added to the system in order for a reaction to occur. If the value of GFE is negative, then the reaction can occur without any outside energy input, whereas a positive value indicates that the reaction requires some external energy input in order to proceed.

GFE also has practical implications for chemists, physicists, engineers, and others who use thermodynamics to design efficient systems. Knowing the GFE of a reaction can help determine the most efficient way to produce a product, as well as the best temperature and pressure conditions to maximize the efficiency of a process. In addition, GFE can also be used to predict the direction of a reaction, which is useful for designing efficient catalysts.

So, to summarize, Gibbs Free Energy can be thought of as the energy that is available to do work after accounting for the energy already present in a system. It is an essential concept in thermodynamics, as it can be used to determine the feasibility of a reaction as well as the amount of energy needed for it to occur. Additionally, GFE has many practical uses in engineering and chemistry, and can be used to design efficient systems and predict the direction of a reaction.


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